|
|
feruloyl-CoA + 16-hydroxypalmitic_acid <=> CoA + 16-feruloyloxypalmitate
|
2.3.1.188
omega-hydroxypalmitate O-feruloyl transferase
|
–
|
MK
|
|
BRENDA:
BR49117
KEGG:
R09106
MetaCyc:
RXN-10749
|
|
|
|
16-hydroxypalmitic_acid + CoA + ATP <=> 16-hydroxypalmitoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
M
|
|
BRENDA:
BS379209
MetaCyc:
RXN-16389
SABIO-RK:
13099
|
|
|
|
sinapoyl-CoA + 16-hydroxypalmitic_acid <=> CoA + (E)-16-(3-(4-hydroxy-3,5-dimethoxyphenyl)acryloyloxy)hexadecanoic_acid
|
2.3.1.188
omega-hydroxypalmitate O-feruloyl transferase
|
–
|
|
|
BRENDA:
BS406664
MetaCyc:
RXN-13728
|
|
|
|
palmitate + reduced_flavodoxin + O2 <=> 16-hydroxypalmitic_acid + flavin + H2O
|
1.14
1.14.14.78
phylloquinone omega-hydroxylase
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
–
–
|
K
|
|
BRENDA:
BS410038
KEGG:
R09451
|
|
|
|
16-hydroxypalmitic_acid + NAD+ <=> 16-oxohexadecanoic_acid + NADH
|
1.1.1.1
alcohol dehydrogenase
|
–
|
|
|
BRENDA:
BS186895
SABIO-RK:
9584
|
|
|
|
16-hydroxypalmitic_acid <=> 16-oxohexadecanoic_acid
|
1.1
|
–
|
K
|
|
KEGG:
R09448
|
|
|
|
16-hydroxypalmitic_acid + NADPH + O2 + H+ <=> 10,16-dihydroxyhexadecanoic_acid + NADP+ + H2O
|
1.14
|
–
|
K
|
|
KEGG:
R09460
|
|
|
|
palmitate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 16-hydroxypalmitic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-16398
|
|
|
|
16-hydroxypalmitic_acid + NADP+ <=> 16-oxohexadecanoic_acid + NADPH + H+
|
1.1.1
|
–
|
M
|
|
MetaCyc:
RXN-9802
|
|
|
|
feruloyl-CoA + 16-hydroxypalmitic_acid <=> CoA + (E)-16-(3-(4-hydroxy-3-methoxyphenyl)acryloyloxy)hexadecanoic_acid
|
2.3.1.188
omega-hydroxypalmitate O-feruloyl transferase
|
–
|
|
|
BRENDA:
BS405136
|
|
|
|
4-coumaroyl-CoA + 16-hydroxypalmitic_acid <=> CoA + (E)-16-(3-(4-hydroxyphenyl)acryloyloxy)hexadecanoic_acid
|
2.3.1.188
omega-hydroxypalmitate O-feruloyl transferase
|
–
|
|
|
BRENDA:
BS406275
|
|
|
|
palmitate + NADH + H+ + O2 <=> 16-hydroxypalmitic_acid + NAD+ + H2O
|
1.14.15.3
alkane 1-monooxygenase
|
–
|
|
|
BRENDA:
BS186756-a
|
|
|
|
palmitate + NADPH + H+ + O2 <=> 16-hydroxypalmitic_acid + NADP+ + H2O
|
1.14.15.3
alkane 1-monooxygenase
|
–
|
|
|
BRENDA:
BS186756
|
|
|
|
cutin + H2O <=> 16-hydroxypalmitic_acid + 10,16-dihydroxyhexadecanoic_acid + 9,10,18-trihydroxyoctadecanoic_acid
|
3.1.1.74
cutinase
|
–
|
|
|
BRENDA:
BS429226
|
|